Photoelectrochemical production of solar fuels

The main activity of this Research Division focuses on the design, synthesis and understanding of different materials for application in devices for the production of solar fuels. Particularly, the team is involved in the study of novel semiconductor and catalytic materials for the photoelectrochemical production of Hydrogen from water splitting, and complex hydrocarbons from CO2 reduction. We are involved in different projects related to the synthesis and characterization of nanostructured materials and complex device architectures based on earth-abundant materials and low-cost synthetic techniques, for industrial relevance. We aim at the understanding of the functional performance of these materials and devices based on the deep analysis of the physico-chemical mechanisms responsible for the device operation. For this purpose, we combine different advanced structural, optical and electrical characterization techniques. Our main objective is revisiting the way that energy is provided.

Short biography of Dr. Giménez

Sixto Giménez (M. Sc. Physics 1996, Ph. D. Physics 2002) is Associate Professor at Universitat Jaume I de Castelló (Spain). His professional career has been focused on the relationship among processing, structure and properties of structural and functional materials. During his PhD thesis at the University of Navarra, he studied the relationship between processing of metallic and ceramic powders, their sintering behavior and mechanical properties. He took a Post-Doc position at the Katholiek Universiteit Leuven (2003-2006) where he focused on the development of non-destructive and in-situ characterization techniques of the sintering behavior of metallic porous materials. In 2006-2007, he was responsible for a new research line on nanostructured particulated materials for magnetic applications at CEIT (Spain). In January 2008, he joined the University Jaume I as a Ramon y Cajal fellow, where he has been involved in the development of new concepts for photovoltaic and photoelectrochemical devices based on nanoscaled materials, particularly studying the optoelectronic and electrochemical responses of the devices. He has co-authored more than 70 scientific papers in international journals and has received more than 3100 citations. He has recently edited a reference book on photoelectrochemical solar fuels production. His current h-index is 26.

At present he is mainly interested in the development of novel materials and devices for the photoelectrochemical production of solar fuels. Particularly, he is involved in the study of metal oxides, organic semiconductors and earth-abundant catalysts for water oxidation and CO2 reduction.

Publications

2024

  1. Nature Reviews Chemistry, 2024,
    Pastor, E.; Lian, Z.; Xia, L.; Ecija, D.; Galán-Mascarós, J.Ramón; Barja, S.; Giménez, S.; Arbiol, J.; López, N.; de Arquer, P.Garcia
    Complementary probes for the electrochemical interface.
    Article page:

2023

  1. Energy & Environmental Science, 2023, 16, 1644-1664.
    Ampelli, C.; Giusi, D.; Miceli, M.; Merdzhanova, T.; Smirnov, V.; Chime, U.; Astakhov, O.; Martin, A.Jose; Veenstra, F.Louise Pet; Pineda, F.Andrés Ga; González-Cobos, J.; Garcia-Tecedor, M.; Giménez, S.; Jaegermann, W.; Centi, G.; Pérez-Ramírez, J.; Galán-Mascarós, J.Ramón; Perathoner, S.
    An artificial leaf device built with earth-abundant materials for combined H 2 production and storage as formate with efficiency> 10%.
    Article page:
  2. Surfaces and Interfaces, 2023, 38, 102813.
    Keshavarzi, R.; Mousavian, M.; Omrani, M.K.; Mirkhani, V.; Afzali, N.; Mesa, C.A.; Mohammadpoor-Baltork, I.; Giménez, S.
    Photoelectrochemical water splitting with dual-photoelectrode tandem and parallel configurations: Enhancing light harvesting and carrier collection efficiencies.
  3. ACS Catalysis, 2023, 13, 10457-10467.
    Fernández-Climent, R.; Redondo, J.; Garcia-Tecedor, M.; Spadaro, M.Chiara; Li, J.; Chartrand, D.; Schiller, F.; Pazos, J.; Hurtado, M.F.; O'Shea, Vde la Peñ; Kornienko, N.; Arbiol, J.; Barja, S.; Mesa, C.A.; Giménez, S.
    Highly Durable Nanoporous Cu2−xS Films for Efficient Hydrogen Evolution Electrocatalysis under Mild pH Conditions.
  4. ACS Catalysis, 2023,
    Fernández-Climent, R.; Redondo, J.; Garcia-Tecedor, M.; Spadaro, M.Chiara; Li, J.; Chartrand, D.; Schiller, F.; Pazos, J.; Hurtado, M.F.; O'Shea, Vde la Peñ; Kornienko, N.; Arbiol, J.; Barja, S.; Mesa, C.A.; Giménez, S.
    Highly Durable Nanoporous Cu2–xS Films for Efficient Hydrogen Evolution Electrocatalysis under Mild pH Conditions.
  5. Inorganic Chemistry Frontiers, 2023,
    Romero, N.; Fenoll, D.A.; Gil, L.; Campos, S.; Creus, J.; Martí, G.; Heras-Domingo, J.; Collière, V.; Mesa, C.A.; Giménez, S.; Francàs, L.; Rodríguez-Santiago, L.; Solans-Monfort, X.; Sodupe, M.; Bofill, R.; Phillippot, K.; García-Antón, J.; Sala, X.
    Ru-based nanoparticles supported on carbon nanotubes for electrocatalytic hydrogen evolution: structural and electronic effects.
  6. Advanced Optical Materials, 2023, 2203096, 1 - 11.
    Gualdrón-Reyes, A.F.; Fernández-Climent, R.; Masi, S.; Mesa, C.A.; Echeverría-Arrondo, C.; Aiello, F.; Balzano, F.; Uccello-Barretta, G.; Rodríguez-Pereira, J.; Giménez, S.; Mora-Seró, I.
    Efficient Ligand Passivation Enables Ultrastable CsPbX3 Perovskite Nanocrystals in Fully Alcohol Environments.
  7. Journal of Catalysis, 2023, 418, 51-63.
    Shaddad, M.N.; Arunachalam, P.; Hezam, M.; BinSaeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
    Facile Fabrication of heterostructured BiPS4-Bi2S3-BiVO4 photoanode for enhanced stability and photoelectrochemical water splitting performance.

2022

  1. Solar RRL, 2022, 6, 202200826.
    Alvarez, A.O.; Garcia-Tecedor, M.; Montañés, L.; Mas-Marzá, E.; Giménez, S.; Fabregat-Santiago, F.
    New Views on Carrier Diffusion and Recombination by Combining Small Perturbation Techniques: Application to BiVO 4 Photoelectrodes.
  2. Angewandte Chemie International Edition, 2022, e202211587.
    Pulignani, C.; Mesa, C.A.; Hillman, S.A.J.; Uekert, T.; Giménez, S.; Durrant, J.Robert; Reisner, E.
    Rational design of carbon nitride photoelectrodes with high activity toward organic oxidations.
  3. ACS Applied Materials and Interfaces, 2022, 14, 33200−33210 .
    Barawi, M.; Gomez-Mendoza, M.; Oropeza, F.E.; Gorni, G.; Villar-García, I.J.; Giménez, S.; O’Shea, V.A. de la P.; Garcia-Tecedor, M.
    Laser-Reduced BiVO4 for Enhanced Photoelectrochemical Water Splitting.
  4. International Journal of Energy Research, 2022, 46, 12608–12622.
    Shaddad, M.N.; Arunachalam, P.; Amer, M.S.; Al-Mayouf, A.M.; Hezam, M.; AlOraij, H.A.; Giménez, S.
    Exploiting the synergistic catalytic effects of CoPi nanostructures on Zr-doped highly ordered TiO2 nanotubes for efficient solar water oxidation.
  5. Advanced Functional Materials, 2022, 2207136,
    Cui, J.; Daboczi, M.; Regue, M.; Chin, Y.C.; Pagano, K.; Zhang, J.; Isaacs, M.A.; Kerherve, G.; Mornto, A.; West, J.; Giménez, S.; Kim, J.S.; Eslava, S.
    2D Bismuthene as a Functional Interlayer between BiVO4 and NiFeOOH for Enhanced Oxygen-Evolution Photoanodes.
  6. Nanoscale, 2022, 14, 15596-15606.
    Pastor, E.; Montañés, L.; Gutierrez-Blanco, A.; Hegner, F.S.; Mesa, C.A.; López, N.; Giménez, S.
    The role of crystal facets and disorder on photoelectrosynthesis.
  7. Nature Communications, 2022, 13, 4341.
    Yu, J.; Garces, F.Andres; González-Cobos, J.; Peña-Díaz, M.; Rogero, C.; Giménez, S.; Spadaro, M.Chiara; Arbiol, J.; Barja, S.; Galán-Mascarós, J.Ramón
    Sustainable oxygen evolution electrocatalysis in aqueous 1 M H2SO4 with earth abundant nanostructured Co3O4.
  8. Materials Letters, 2022, 325, 132799.
    Shaddad, M.N.; Hezam, M.; Arunachalam, P.; AL-Saeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
    Improved Solar Water Splitting Performance of BiVO4 Photoanode by the Synergistic Effect of Zr-Mo co-doping and FeOOH Co-catalyst layer.
  9. Journal of American Chemical Society, 2022,
    Rao, R.; Corby, S.; Bucci, A.; Garcia-Tecedor, M.; Mesa, C.A.; Rossmeisl, J.; Giménez, S.; Lloret-Fillol, J.; Stephens, I.E.L.; Durrant, J.Robert
    Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides.
    Article page:
  10. Solar RRL, 2022, 2200012, 1-16.
    Gualdrón-Reyes, A.F.; Mesa, C.A.; Giménez, S.; Mora-Seró, I.
    Application of Halide Perovskite Nanocrystals in Solar- Driven Photo(electro)Catalysis.
  11. Solar RRL, 2022, 6, 2200132.
    Arcas, R.; Cardenas-Morcoso, D.; Spadaro, M.Chiara; Garcia-Tecedor, M.; Mesa, C.A.; Arbiol, J.; Fabregat-Santiago, F.; Giménez, S.; Mas-Marzá, E.
    Direct observation of the chemical transformations in BiVO4 photoanodes upon prolonged light-aging treatments.
  12. Advanced Sustainable Systems, 2022, 2100367.
    Carvajal, D.; Arcas, R.; Mesa, C.A.; Giménez, S.; Fabregat-Santiago, F.; Mas-Marzá, E.
    Role of Pd in the electrochemical hydrogenation of nitrobenzene using CuPd electrodes.

2021

  1. Solar RRL, 2021, 2100723, 1-8.
    Fernández-Climent, R.; Gualdrón-Reyes, A.F.; Garcia-Tecedor, M.; Mesa, C.A.; Cardenas-Morcoso, D.; Montañés, L.; Barea, E.M.; Mas-Marzá, E.; Julián-López, B.; Mora-Seró, I.; Giménez, S.
    Switchable All Inorganic Halide Perovskite Nanocrystalline Photoelectrodes for Solar-Driven Organic Transformations.
  2. Chemistry of Materials, 2021, 33, 22, 8745–8757.
    Lee, C.H.; Shin, Y.J.; Villanueva-Antolí, A.; Adhikari, S.Das; Rodríguez-Pereira, J.; Macak, J.M.; Mesa, C.A.; Giménez, S.; Yoon, S.Joon; Gualdrón-Reyes, A.F.; Mora-Seró, I.
    Efficient and Stable Blue- and Red-Emitting Perovskite Nanocrystals through Defect Engineering: PbX2 Purification.
  3. Catalysts, 2021, 11, 1244.
    Montañés, L.; Mesa, C.A.; Gutierrez-Blanco, A.; Robles, C.; Julián-López, B.; Giménez, S.
    Facile Surfactant-Assisted Synthesis of BiVO4 Nanoparticulate Films for Solar Water Splitting.
  4. International Journal of Hydrogen Energy, 2021, 46, 23702-23714.
    Shaddad, M.N.; Arunachalam, P.; Hezam, M.; AL-Saeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
    Unprecedented solar water splitting of dendritic nanostructured Bi2O3 films by combined oxygen vacancy formation and Na2MoO4 doping.
  5. Applied Materials Today, 2021, 24, 101159 .
    Afzali, N.; Keshavarzi, R.; Tangestaninejad, S.; Giménez, S.; Mirkhani, V.; Moghadam, M.; Mohammadpoor-Baltork, I.
    Multifunctional approach to improve water oxidation performance with MOF-based photoelectrodes.
  6. Journal of Materials Chemistry A, 2021,
    Bucci, A.; Garcia-Tecedor, M.; Corby, S.; Rao, R.; Martin-Diaconescu, V.; Oropeza, F.; O'Shea, V.Antonio An; Durrant, J.Robert; Giménez, S.; Lloret-Fillol, J.
    Self-Supported Ultra-Active NiO-Based Electrocatalysts for Oxygen Evolution Reaction by Solution Combustion.
  7. ACS Applied Energy Materials, 2021,
    Noguera, J.; Garcia-Tecedor, M.; Royo, J.Francisco; Liñan, L.María Val; de la Mata, M.; Herrera-Collado, M.; Molina, S.I.; Abargues, R.; Giménez, S.
    Solution-processed Ni-based nanocomposite electrocatalysts: An approach to highly efficient Electrochemical Water Splitting.
    Article page:
  8. ACS Applied Materials and Interfaces, 2021,
    Kim, T.Y.; Kim, B.Su; Oh, J.Gyu; Park, S.Chan; Jang, J.; Hamann, T.; Kang, Y.Soo; Bang, J.Ho; Giménez, S.; Kang, Y.Soo
    Interfacial Engineering at Quantum Dot-Sensitized TiO2 Photoelectrodes for Ultrahigh Photocurrent Generation.
    Article page:
  9. ChemSusChem, 2021, 14,
    Garcés-Pineda, F.Andrés; Nguyën, H.Chuong; Blasco-Ahicart, M.; Garcia-Tecedor, M.; Febré, Mde Fez; Tang, P.Y.; Arbiol, J.; Giménez, S.; Galán-Mascarós, J.Ramón; López, N.
    Push-pull electronic effects in surface active sites enhance electrocatalytic oxygen evolution on transition metal oxides.

2020

  1. Sustainable Energy & Fuels, 2020, 4, 6227-6233.
    Han, L.; González-Cobos, J.; Sánchez-Molina, I.; Giancola, S.; Folkman, S.J.; Giménez, S.; Vidal-Ferran, A.; Mascaros, J.Ram´on Ga
    A low temperature aqueous formate fuel cell using cobalt hexacyanoferrate as a non-noble metal oxidation catalyst.
  2. ACS Sustainable Chemistry & Engineering, 2020, 8, 18366−18376.
    Afzali, N.; Tangestaninejad, S.; Keshavarzi, R.; Mirkhani, V.; Nematollahi, J.; Moghadam, M.; Mohammadpoor-Baltork, I.; Reimer, M.; Olthof, S.; Klein, A.; Giménez, S.
    Hierarchical Ti-Based MOF with Embedded RuO2 Nanoparticles: a Highly Efficient Photoelectrode for Visible Light Water Oxidation.
  3. Sustainable Energy & Fuels, 2020, 4, 5024-5030.
    Corby, S.; Garcia-Tecedor, M.; Tengeler, S.; Steinert, C.; Moss, B.; Mesa, C.A.; Heiba, H.F.; Wilson, A.A.; Kaiser, B.; Jaegermann, W.; Francàs, L.; Giménez, S.; Durrant, J.Robert
    Separating Bulk and Surface Processes in NiOx Electrocatalysts for Water Oxidation.
  4. Sustainable Energy & Fuels, 2020,
    Fernández-Climent, R.; Giménez, S.; Garcia-Tecedor, M.
    The Role of Oxygen Vacancies on Water Splitting Photoanodes.
  5. Materials Advances, 2020, 1, 1202-1211.
    Cardenas-Morcoso, D.; Garcia-Tecedor, M.; Merdzhanova, T.; Smirnov, V.; Finger, F.; Kaiser, B.; Jaegermann, W.; Giménez, S.
    An Integrated Photoanode Based on Non-Critical Raw Materials for Robust Solar Water Splitting.
  6. ACS Applied Energy Materials, 2020,
    Han, L.; González-Cobos, J.; Sánchez-Molina, I.; Giancola, S.; Folkman, S.J.; Tang, P.; Heggen, M.; Dunin-Borkowski, R.E.; Arbiol, J.; Giménez, S.; Galán-Mascarós, J.Ramón
    Cobalt hexacyanoferrate as a selective and high current densi-ty formate oxidation electrocatalyst.
    Article page:
  7. Applied Materials Today, 2020, 20, 100714.
    Barrio, J.; Gibaja, C.; Garcia-Tecedor, M.; Abisdris, L.; Torres, I.; Karjule, N.; Giménez, S.; Shalom, M.; Zamora, F.
    Electrophoretic deposition of antimonene for photoelectrochemical applications.
  8. Energy Technology, 2020, 8, 2000301.
    Lemsi, A.; Cardenas-Morcoso, D.; Haro, M.; Gil-Barrachina, C.; Aranda, C.; Maghraoui-Meherzi, H.; Garcia-Tecedor, M.; Giménez, S.; Julián-López, B.
    PbS nanocubes for solar energy storage.
  9. ACS Energy Letters, 2020, 5, 187-191.
    Cardenas-Morcoso, D.; Bou, A.; Ravishankar, S.; Garcia-Tecedor, M.; Giménez, S.; Bisquert, J.
    Intensity-Modulated Photocurrent Spectroscopy for Solar Energy Conversion Devices: What Does a Negative Value Mean?.
  10. ACS Applied Materials and Interfaces, 2020, 12, 914−924.
    Gualdrón-Reyes, A.F.; Rodríguez-Pereira, J.; Amado-Gonzalez, E.; Rueda-P, J.; Ospina, R.; Masi, S.; Yoon, S.Joon; Tirado, J.; Jaramillo, F.; Agouram, S.; Muñoz-Sanjose, V.; Giménez, S.; Mora-Seró, I.
    Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States.

2019

  1. ACS Omega, 2019, 4, 14, 16095−16102.
    Shaddad, M.N.; Cardenas-Morcoso, D.; Garcia-Tecedor, M.; Fabregat-Santiago, F.; Bisquert, J.; Al-Mayouf, A.M.; Giménez, S.
    TiO2 Nanotubes for Solar Water Splitting: Vacuum Annealing and Zr Doping Enhance Water Oxidation Kinetics.
  2. Journal of American Chemical Society, 2019, 141, 47, 18791−18798.
    Selim, S.; Pastor, E.; Garcia-Tecedor, M.; Morris, M.R.; Francàs, L.; Sachs, M.; Moss, B.; Corby, S.; Mesa, C.A.; Giménez, S.; Kafizas, A.; Bakulin, A.A.; Durrant, J.Robert
    Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes.
  3. ACS Applied Materials and Interfaces, 2019, 8,11, 16546-16555.
    Liu, K.; Wu, L.; Valenti, M.; Cardenas-Morcoso, D.; Hofmann, J.Philipp; Bisquert, J.; Giménez, S.; Smith, W.A.
    Electronic effects determine the selectivity of planar Au-Cu bimetallic thin films for electrochemical CO2 reduction.
  4. ACS Catalysis, 2019, 9, 3527−3536.
    Valenti, M.; Prasad, N.P.; Kas, R.; Bohra, D.; Ma, M.; Balasubramanian, V.; Chu, L.; Giménez, S.; Bisquert, J.; Dam, B.; Smith, W.A.
    Suppressing H2 Evolution and Promoting Selective CO2 Electroreduction to CO at Low Overpotentials by Alloying Au with Pd.
  5. Advanced Materials Interfaces, 2019, 1900299, 1-8.
    Garcia-Tecedor, M.; Cardenas-Morcoso, D.; Fernández-Climent, R.; Giménez, S.
    The Role of Underlayers and Overlayers in Thin Film BiVO4 Photoanodes for Solar Water Splitting.
  6. Journal of Materials Chemistry A, 2019, 7, 11143-11149.
    Cardenas-Morcoso, D.; Ifraemov, R.; Garcia-Tecedor, M.; Liberman, I.; Giménez, S.; Hod, I.
    A Metal-Organic Framework Converted Catalyst that Boosts Photo-Electrochemical Water Splitting.
  7. Chemical Science, 2019, 10 (9), 2643-2652.
    Selim, S.; Francàs, L.; Garcia-Tecedor, M.; Corby, S.; Blackman, C.; Giménez, S.; Durrant, J.Robert; Kafizas, A.
    WO3/BiVO4: impact of charge separation at the timescale of water oxidation.
  8. ACS Energy Letters, 2019, 4, 337−342.
    Moss, B.; Hegner, F.Simone; Corby, S.; Selim, S.; Francàs, L.; López, N.; Giménez, S.; Galán-Mascarós, J.Ramón; Durrant, J.Robert
    Unraveling Charge Transfer in CoFe Prussian Blue Modified BiVO4 Photoanodes.
  9. The Journal of Physical Chemistry Letters, 2019, 10, 630-636.
    Cardenas-Morcoso, D.; Gualdrón-Reyes, A.F.; Vitoreti, A.Beatriz Fe; Garcia-Tecedor, M.; Yoon, S.Joon; de la Fuente, M.Solis; Mora-Seró, I.; Giménez, S.
    Photocatalytic and Photoelectrochemical Degradation of Organic Compounds with All-Inorganic Metal Halide Perovskite Quantum Dots.

2018

  1. ChemSusChem, 2018, 11, 1797– 1804.
    Perez-Rodriguez, P.; Cardenas-Morcoso, D.; Digdaya, I.A.; Raventos, A.Mangel; Procel, P.; Isabella, O.; Giménez, S.; Zeman, M.; Smith, W.A.; Smets, A.H.M.
    Improving the Back Surface Field on an Amorphous Silicon Carbide Thin-Film Photocathode for Solar Water Splitting.
  2. The Journal of Physical Chemistry C, 2018, 122, 11608−11615.
    Shaddad, M.N.; Cardenas-Morcoso, D.; Arunachalam, P.; Garcia-Tecedor, M.; Ghanem, M.A.; Bisquert, J.; Al-Mayouf, A.M.; Giménez, S.
    Enhancing the Optical Absorption and Interfacial Properties of BiVO4 with Ag3PO4 Nanoparticles for Efficient Water Splitting.
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