Principal Investigator:
The research program of the group is focused in the development of advanced hybrid materials for energy conversion and storage based on catalytic transformations.
The hybrid materials are developed from well-defined organometallic complexes. The approach for such applications is divided on three different research lines: i) Organometallic chemistry: design, characterisation and properties of new catalysts ii) Catalytic applications in processes related to hydrogenation and dehydrogenation. iii) New materials: study of the properties and applications of organometallic compounds and metal nanoparticles supported in graphene derivatives for energy conversion and storage.
Research Lines:
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Ad. Mat. for catalysis
- Rationale design of catalytic materials derived from organometallic complexes.
- Development of stable metal nanoparticles as improved catalytic systems.
- Ligand design for the immobilization of metal complexes and nanoparticles.
- Fundamental and applied study of catalytic hydrogenation and dehydrogenation processes.
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Ad. Mat. for energy storage
- Development of systems for the storage of hydrogen in the liquid form using “Liquid Organic Hydrogen Carriers (LOHCs).
- Development of Hydrogen Storage technologies for transport and uses of hydrogen.
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Industrial Innovation and Technology Transfer
- The group is involved in industrial projects on Hydrogen Storage, depolymerization processes and catalyst development in connection with a regional funding program (AVI).
Members
Publications
2018
ACS Catalysis,
2018,
8,
2558−2566.
High Production of Hydrogen on Demand from Silanes Catalyzed by Iridium Complexes as a Versatile Hydrogen Storage System.
Article page: https://pubs.acs.org/doi/abs/10.1021/acscatal.7b04479
2017
Journal of Catalysis,
2017,
352,
498 – 504.
Enhancement of gold catalytic activity and stability by immobilization on the surface of graphene.
Chemistry - A European Journal,
2017,
45,
10815 – 10821.
Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier..
2016
European Journal of Inorganic Chemistry,
2016,
17,
2667 – 2675.
Multiple-Metal (De-)Hydrogenation-Catalysed Processes.
Scientific Reports,
2016,
6,
1-9.
In situ decoration of graphene sheets with gold nanoparticles synthetized by pulsed laser ablation in liquids.
Chemistry - A European Journal,
2016,
22,
17758 – 17766.
Catalytic hydrogen production by ruthenium complexes from the conversion of primary amines to nitriles: Potential application as liquid organic hydrogen carrier..
Catalysis Science & Technology,
2016,
6,
8024-8035.
Ruthenium molecular complexes immobilized on graphene as active catalysts for the synthesis of carboxylic acids from alcohol dehydrogenation..