Principal Investigator: 

The main work on the team is the investigation and modeling of fundamental mechanisms governing the operation of light to energy conversion in semiconductor materials and devices. The research program is about perovskite solar cells, other emerging solar cells and water splitting with visible light and semiconductors. The team combines experimental investigation and theoretical and numerical tools to develop insights in the electronic processes in hybrid organic-inorganic solar cells, joining novel theory of semiconductor nanostructures, photoelectrochemistry, and systematic experimental demonstration.

Specific lines of research:

  • Ad. Mat. for energy conversion.
    • Developing complete electrical devices for optoelectronics, photovoltaics, energy storage, and sensoring. Particularly relevant for the research developed is parameter extraction and mechanism identification inferred from impedance spectroscopy analysis.
    • Characterization and understanding of the distinctive properties of halide perovskite materials and devices in broad contexts and application in optoelectronic devices.
    • Synthesis of high-quality thin films and single crystals perovskites by understanding the crystallization properties of the material that enables the study of the fundamental properties of perovskites.
    • Understanding connections between structural, thermodynamic, and kinetic aspects, and electrical behavior and new functionalities of novel materials and interfaces.
    • Developing models for photoelectrochemical conversion of water to fuel, using impedance spectroscopy to characterize the interfacial processes at the electrochemical junction.
    • Testing and degradation diagnostics of materials for energy storage (batteries) using impedance spectroscopy. Analysis of charging processes in battery electrodes.
  • Ad. Mat. for catalysis.
    • Developing new materials for catalytic applications in electrochemical reactions. Design and synthesis of new materials to efficiently promote the water splitting. Morphological and chemical characterization of these materials with particular attention to formation of active species.
    • Implementation of photovoltaic devices into a photoelectromical configuration. Stabilization of perovskites in liquids, study of protecting layers and compatibility with catalysts. Electrical characterization of these systems and analysis and modelling of key processes.
  • Industrial Innovation and Technology Transfer

The group has been involved in industrial projects on catalysis in connection with a regional funding program (AVI) where catalysts have been developed for the water splitting reaction. In addition, the group has worked on an industrially funded project related to passive radiative cooling of buildings.

more info: amsy.es

Members

Juan Bisquert's picture
Juan Bisquert

Senior Researcher

Antonio Guerrero's picture
Antonio Guerrero

Senior Researcher

So-Yeon Kim's picture
So-Yeon Kim

Research Scientist

Naresh Kumar Pendyala's picture
Naresh Kumar Pendyala

Research Scientist

Sitavro Mandal's picture
Sitavro Mandal

Doctoral Candidate

Heyi Zhang's picture
Heyi Zhang

Doctoral Candidate

Publications


2023

Synthetic Metals, 2023, 295, 117347.
Rozhkova, X.; Aimukhanov, A.; Guerrero, A.; Bisquert, J.; Alexeev, A.; Zeinidenov, A.; Paygin, V.; Valiev, D.; Ilyassov, B.
Nanocomposition of PEDOT:PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaics. The Journal of Physical Chemistry Letters, 2023, 14, 1014–1021.
Bisquert, J.
Electrical Charge Coupling Dominates the Hysteresis Effect of Halide Perovskite Devices. ACS Physical Chemistry Au, 2023, 3, 386-393.
Alvarez, A.O.; Lédée, F.; García-Batlle, M.; Lopez-Varo, P.; Gros-Daillon, E.; Guillén, J.Mayén; Verilhac, J.M.; Lemercier, T.; Zaccaro, J.; Marsal, L.F.; Garcia-Belmonte, G.; Almora, O.
Ionic Field Screening in MAPbBr3 Crystals Revealed from Remnant Sensitivity in X-ray Detection. Journal of Catalysis, 2023, 418, 51-63.
Shaddad, M.N.; Arunachalam, P.; Hezam, M.; BinSaeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
Facile Fabrication of heterostructured BiPS4-Bi2S3-BiVO4 photoanode for enhanced stability and photoelectrochemical water splitting performance. Solar Energy Materials & Solar Cells, 2023, 251, 112115.
Tsarev, S.; Dubinina, T.; Olthof, S.; Guerrero, A.; Luchkin, S.Yu; Bisquert, J.; Troshin, P.
Stabilizing perovskite solar cells with modified indium oxide electron transport layer. Advanced Materials, 2023, 35, 2207993.
Sánchez, R.S.; Villanueva-Antolí, A.; Bou, A.; Ruiz-Murillo, M.; Mora-Seró, I.; Bisquert, J.
Radiative recombination processes in halide perovskites observed by light emission voltage modulated spectroscopy.


2022

Chemical Engineering Journal, 2022, 446, P3, 137164.
Bi, Z.; Xu, X.; Chen, X.; Zhu, Y.; Liu, C.; Yu, H.; Zheng, Y.; Troshin, P.A.; Guerrero, A.; Xu, G.
High-performance large-area blade-coated perovskite solar cells with low ohmic loss for low lighting indoor applications. ACS Energy Letters, 2022, 7, 3, 1214-1222.
Berruet, M.; Pérez-Martínez, J.Carlos; Romero, B.; Gonzales, C.; Al-Mayouf, A.M.; Guerrero, A.; Bisquert, J.
Physical Model for the Current–Voltage Hysteresis and Impedance of Halide Perovskite Memristors. The Journal of Physical Chemistry Letters, 2022, 13, 7320–7335.
Bisquert, J.
Interpretation of the Recombination Lifetime in Halide Perovskite Devices by Correlated Techniques. Solar RRL, 2022, 6, 2200737.
Zheng, Y.; Xu, X.; Liu, S.; Bi, Z.; Zhu, Y.; Guerrero, A.; Xing, G.
Blade‐Coating High‐Quality Formamidinium‐Cesium Lead Halide Perovskites with Green Solvent for Efficient and Stable Solar Cells. The Journal of Physical Chemistry C, 2022, 126, 13560.
Gonzales, C.; Guerrero, A.; Bisquert, J.
Transition from capacitive to inductive hysteresis: A neuron-style model to correlate I-V curves to impedances of metal halide perovskites. ACS Energy Letters, 2022, 7, 3401–3414.
Sakhatskyi, K.; Guerrero, A.; Bisquert, J.; Kovalenko, M.V.
Assessing the Drawbacks and Benefits of Ion Migration in Lead Halide Perovskites. Chemical Physics Reviews, 2022, 3, 041305.
Bisquert, J.
Negative inductor effects in nonlinear two-dimensional systems: Oscillatory neurons and memristors. Advanced Photonics Research, 2022, 3, 2200136.
García-Batlle, M.; Deumel, S.; Huerdler, J.E.; Tedde, S.F.; Almora, O.; Garcia-Belmonte, G.
Effective Ion Mobility and Long-Term Dark Current of Metal Halide Perovskites with Different Crystallinities and Compositions. ACS Energy Letters, 2022, 7, 2602–2610.
Hernández-Balaguera, E.; Bisquert, J.
Negative Transient Spikes in Halide Perovskites. Frontiers in Energy, 2022, 10, 914115.
Munoz-Diaz, L.; Rosa, A.J.; Bou, A.; Sánchez, R.S.; Romero, B.; John, R.Abraham; Kovalenko, M.V.; Guerrero, A.; Bisquert, J.
Inductive and Capacitive Hysteresis of Halide Perovskite Solar Cells and Memristors Under Illumination. Materials Letters, 2022, 325, 132799.
Shaddad, M.N.; Hezam, M.; Arunachalam, P.; AL-Saeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
Improved Solar Water Splitting Performance of BiVO4 Photoanode by the Synergistic Effect of Zr-Mo co-doping and FeOOH Co-catalyst layer. Solar RRL, 2022, 6, 2200173.
García-Batlle, M.; Zia, W.; Aranda, C.; Saliba, M.; Almora, O.; Guerrero, A.; Garcia-Belmonte, G.
Observation of Long-Term Stable Response in MAPbBr3 Single Crystals Monitored through Displacement Currents under Varying Illumination. APL Materials, 2022, 10, 051104.
Bou, A.; Pockett, A.; Cruanyes, H.; Raptis, D.; Watson, T.M.; Carnie, M.J.; Bisquert, J.
Limited information of impedance spectroscopy about electronic diffusion transport: The case of perovskite solar cells. The Journal of Physical Chemistry Letters, 2022, 13, 3130–3137.
Sahamir, S.Razey; Ripolles, T.S.; Segawa, H.; Shen, Q.; Bisquert, J.; Hayase, S.
Enhancing the Electronic Properties and Stability of High-Efficiency Tin–Lead Mixed Halide Perovskite Solar Cells via Doping Engineering.