Principal Investigator: 

The main interest of the group is to develop advanced luminescent nanomaterials, including both inorganic and hybrid organic–inorganic materials, with tailored structure and properties, for applications in photonics, energy, ceramics and catalysis. The team has a broad expertise in the design, synthesis and characterization of nanostructured materials based on metal oxides, metal halides and hybrid organic-inorganic siloxanes, by using Soft-Chemistry routes and self-assembly strategies. Our current efforts focus on developing smart systems integrating lanthanide ions, due to their unique optical properties (up- and down-conversion, energy transfer, cooperative effects, etc…), but also on optical absorbers and emitting materials such as mixed metal transition oxides or hybrid halide perovskites for solar fuels, photoelectrocatalysis and displays. Specific lines of research:

  • Adv. Mat.for light emission.
    • Soft chemistry synthesis (sol-gel, solvothermal, microwave, etc.) and structural characterization of luminescent hierarchical nanostructures.
    • Fundamental understanding of the solution chemistry and mechanisms of formation of nanocrystals and nanostructured materials.
    • Design of systems with tailored properties, in terms of chemical behaviour, nanostructure and luminescence. In particular, materials with up-conversion, down-conversion, down-shifting and energy transfer processes coupled with other functional properties.
    • Develop functional materials able to be integrated in different media such as polymers, glasses, ceramics or hybrid organic-inorganic coatings, for their application in the fields of energy conversion, integrated optics, lighting and displays, photo-(electro)catalysis, bioimaging, or security applications.
  • Industrial Innovation and Technology Transfer

The group has been involved in industrial projects on luminescent materials as markers for sustainable plastics recycling and anti-fraud in connection with a regional funding program (AVI). Some of the materials developed are under study with companies for further deployment.

Members

Sixto Giménez's picture
Sixto Giménez

Senior Researcher

Beatriz Julian-Lopez's picture
Beatriz Julian-Lopez

Senior Researcher

Javier Durantini's picture
Javier Durantini

Research Scientist

Ana María Gutierrez Blanco's picture
Ana María Gutierrez Blanco

Research Scientist

Lakshman Sundar Arumugam's picture
Lakshman Sundar Arumugam

Doctoral Candidate

Gabriel Marius Burcea Mutcu's picture
Gabriel Marius Burcea Mutcu

Doctoral Candidate

Thais Caroline de Almeida da Silva's picture
Thais Caroline de Almeida da Silva

Doctoral Candidate

Lorenzo Forzanini's picture
Lorenzo Forzanini

Doctoral Candidate

Samiksha Mukesh Jain's picture
Samiksha Mukesh Jain

Doctoral Candidate

Eva Ng's picture
Eva Ng

Doctoral Candidate

Christian Robles's picture
Christian Robles

Doctoral Candidate

Radeya Vasquez's picture
Radeya Vasquez

Doctoral Candidate

Alejandro Saura Avilés's picture
Alejandro Saura Avilés

Graduate Student

PAOLA BALAGUER's picture
PAOLA BALAGUER

Undergraduate Student

Sergio Simarro Ruiz

Undergraduate Student

Publications


2024

Chemistry of Materials, 2024,
Reyes-Francis, E.; Echeverría-Arrondo, C.; Esparza, D.; Lopez-Luke, T.; Soto-Montero, T.; Morales-Masis, M.; Turren-Cruz, S.H.; Mora-Seró, I.; Julián-López, B.
Microwave-Mediated Synthesis of Lead-Free Cesium Titanium Bromide Double Perovskite: A Sustainable Approach. Nature Reviews Chemistry, 2024,
Pastor, E.; Lian, Z.; Xia, L.; Ecija, D.; Galán-Mascarós, J.Ramón; Barja, S.; Giménez, S.; Arbiol, J.; López, N.; de Arquer, P.Garcia
Complementary probes for the electrochemical interface.


2023

Energy & Environmental Science, 2023, 16, 1644-1664.
Ampelli, C.; Giusi, D.; Miceli, M.; Merdzhanova, T.; Smirnov, V.; Chime, U.; Astakhov, O.; Martin, A.Jose; Veenstra, F.Louise Pet; Pineda, F.Andrés Ga; González-Cobos, J.; Garcia-Tecedor, M.; Giménez, S.; Jaegermann, W.; Centi, G.; Pérez-Ramírez, J.; Galán-Mascarós, J.Ramón; Perathoner, S.
An artificial leaf device built with earth-abundant materials for combined H 2 production and storage as formate with efficiency> 10%. Surfaces and Interfaces, 2023, 38, 102813.
Keshavarzi, R.; Mousavian, M.; Omrani, M.K.; Mirkhani, V.; Afzali, N.; Mesa, C.A.; Mohammadpoor-Baltork, I.; Giménez, S.
Photoelectrochemical water splitting with dual-photoelectrode tandem and parallel configurations: Enhancing light harvesting and carrier collection efficiencies. ACS Catalysis, 2023, 13, 10457-10467.
Fernández-Climent, R.; Redondo, J.; Garcia-Tecedor, M.; Spadaro, M.Chiara; Li, J.; Chartrand, D.; Schiller, F.; Pazos, J.; Hurtado, M.F.; O'Shea, Vde la Peñ; Kornienko, N.; Arbiol, J.; Barja, S.; Mesa, C.A.; Giménez, S.
Highly Durable Nanoporous Cu2−xS Films for Efficient Hydrogen Evolution Electrocatalysis under Mild pH Conditions. ACS Catalysis, 2023,
Fernández-Climent, R.; Redondo, J.; Garcia-Tecedor, M.; Spadaro, M.Chiara; Li, J.; Chartrand, D.; Schiller, F.; Pazos, J.; Hurtado, M.F.; O'Shea, Vde la Peñ; Kornienko, N.; Arbiol, J.; Barja, S.; Mesa, C.A.; Giménez, S.
Highly Durable Nanoporous Cu2–xS Films for Efficient Hydrogen Evolution Electrocatalysis under Mild pH Conditions. Inorganic Chemistry Frontiers, 2023,
Romero, N.; Fenoll, D.A.; Gil, L.; Campos, S.; Creus, J.; Martí, G.; Heras-Domingo, J.; Collière, V.; Mesa, C.A.; Giménez, S.; Francàs, L.; Rodríguez-Santiago, L.; Solans-Monfort, X.; Sodupe, M.; Bofill, R.; Phillippot, K.; García-Antón, J.; Sala, X.
Ru-based nanoparticles supported on carbon nanotubes for electrocatalytic hydrogen evolution: structural and electronic effects. Journal of Sol-Gel Science and Technology, 2023, 06171-1.
da Silva, T.D.A.; Fernández-Saiz, C.; Sánchez, R.S.; Gualdrón-Reyes, A.F.; Mora-Seró, I.; Julián-López, B.
A sustainable soft-chemistry route to prepare halide perovskite nanocrystals with tunable emission and high optical performance. Advanced Optical Materials, 2023, 2203096, 1 - 11.
Gualdrón-Reyes, A.F.; Fernández-Climent, R.; Masi, S.; Mesa, C.A.; Echeverría-Arrondo, C.; Aiello, F.; Balzano, F.; Uccello-Barretta, G.; Rodríguez-Pereira, J.; Giménez, S.; Mora-Seró, I.
Efficient Ligand Passivation Enables Ultrastable CsPbX3 Perovskite Nanocrystals in Fully Alcohol Environments. Journal of Catalysis, 2023, 418, 51-63.
Shaddad, M.N.; Arunachalam, P.; Hezam, M.; BinSaeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
Facile Fabrication of heterostructured BiPS4-Bi2S3-BiVO4 photoanode for enhanced stability and photoelectrochemical water splitting performance.


2022

Solar RRL, 2022, 6, 202200826.
Alvarez, A.O.; Garcia-Tecedor, M.; Montañés, L.; Mas-Marzá, E.; Giménez, S.; Fabregat-Santiago, F.
New Views on Carrier Diffusion and Recombination by Combining Small Perturbation Techniques: Application to BiVO 4 Photoelectrodes. Electrochimica Acta, 2022, 439, 141701.
Solis, O.E.; Fernández-Saiz, C.; Rivas, J.Manuel; Esparza, D.; Turren-Cruz, S.H.; Julián-López, B.; Boix, P.P.; Mora-Seró, I.
α-FAPbI3 powder presynthesized by microwave irradiation for photovoltaic applications. Angewandte Chemie International Edition, 2022, e202211587.
Pulignani, C.; Mesa, C.A.; Hillman, S.A.J.; Uekert, T.; Giménez, S.; Durrant, J.Robert; Reisner, E.
Rational design of carbon nitride photoelectrodes with high activity toward organic oxidations. ACS Applied Materials and Interfaces, 2022, 14, 33200−33210 .
Barawi, M.; Gomez-Mendoza, M.; Oropeza, F.E.; Gorni, G.; Villar-García, I.J.; Giménez, S.; O’Shea, V.A. de la P.; Garcia-Tecedor, M.
Laser-Reduced BiVO4 for Enhanced Photoelectrochemical Water Splitting. International Journal of Energy Research, 2022, 46, 12608–12622.
Shaddad, M.N.; Arunachalam, P.; Amer, M.S.; Al-Mayouf, A.M.; Hezam, M.; AlOraij, H.A.; Giménez, S.
Exploiting the synergistic catalytic effects of CoPi nanostructures on Zr-doped highly ordered TiO2 nanotubes for efficient solar water oxidation. Advanced Functional Materials, 2022, 2207136,
Cui, J.; Daboczi, M.; Regue, M.; Chin, Y.C.; Pagano, K.; Zhang, J.; Isaacs, M.A.; Kerherve, G.; Mornto, A.; West, J.; Giménez, S.; Kim, J.S.; Eslava, S.
2D Bismuthene as a Functional Interlayer between BiVO4 and NiFeOOH for Enhanced Oxygen-Evolution Photoanodes. Nanoscale, 2022, 14, 15596-15606.
Pastor, E.; Montañés, L.; Gutierrez-Blanco, A.; Hegner, F.S.; Mesa, C.A.; López, N.; Giménez, S.
The role of crystal facets and disorder on photoelectrosynthesis. Nature Communications, 2022, 13, 4341.
Yu, J.; Garces, F.Andres; González-Cobos, J.; Peña-Díaz, M.; Rogero, C.; Giménez, S.; Spadaro, M.Chiara; Arbiol, J.; Barja, S.; Galán-Mascarós, J.Ramón
Sustainable oxygen evolution electrocatalysis in aqueous 1 M H2SO4 with earth abundant nanostructured Co3O4. Materials Letters, 2022, 325, 132799.
Shaddad, M.N.; Hezam, M.; Arunachalam, P.; AL-Saeedan, N.M.; Giménez, S.; Bisquert, J.; Al-Mayouf, A.M.
Improved Solar Water Splitting Performance of BiVO4 Photoanode by the Synergistic Effect of Zr-Mo co-doping and FeOOH Co-catalyst layer. Journal of American Chemical Society, 2022,
Rao, R.; Corby, S.; Bucci, A.; Garcia-Tecedor, M.; Mesa, C.A.; Rossmeisl, J.; Giménez, S.; Lloret-Fillol, J.; Stephens, I.E.L.; Durrant, J.Robert
Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides.
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