Principal Investigator: 

The main interest of the group is to develop advanced luminescent nanomaterials, including both inorganic and hybrid organic–inorganic materials, with tailored structure and properties, for applications in photonics, energy, ceramics and catalysis. The team has a broad expertise in the design, synthesis and characterization of nanostructured materials based on metal oxides, metal halides and hybrid organic-inorganic siloxanes, by using Soft-Chemistry routes and self-assembly strategies. Our current efforts focus on developing smart systems integrating lanthanide ions, due to their unique optical properties (up- and down-conversion, energy transfer, cooperative effects, etc…), but also on optical absorbers and emitting materials such as mixed metal transition oxides or hybrid halide perovskites for solar fuels, photoelectrocatalysis and displays. Specific lines of research:

  • Adv. Mat.for light emission.
    • Soft chemistry synthesis (sol-gel, solvothermal, microwave, etc.) and structural characterization of luminescent hierarchical nanostructures.
    • Fundamental understanding of the solution chemistry and mechanisms of formation of nanocrystals and nanostructured materials.
    • Design of systems with tailored properties, in terms of chemical behaviour, nanostructure and luminescence. In particular, materials with up-conversion, down-conversion, down-shifting and energy transfer processes coupled with other functional properties.
    • Develop functional materials able to be integrated in different media such as polymers, glasses, ceramics or hybrid organic-inorganic coatings, for their application in the fields of energy conversion, integrated optics, lighting and displays, photo-(electro)catalysis, bioimaging, or security applications.
  • Industrial Innovation and Technology Transfer

The group has been involved in industrial projects on luminescent materials as markers for sustainable plastics recycling and anti-fraud in connection with a regional funding program (AVI). Some of the materials developed are under study with companies for further deployment.

Members

Sixto Giménez's picture
Sixto Giménez

Senior Researcher

Beatriz Julian-Lopez's picture
Beatriz Julian-Lopez

Senior Researcher

Javier Durantini's picture
Javier Durantini

Research Scientist

Ana María Gutierrez Blanco's picture
Ana María Gutierrez Blanco

Research Scientist

Lakshman Sundar Arumugam's picture
Lakshman Sundar Arumugam

Doctoral Candidate

Gabriel Marius Burcea Mutcu's picture
Gabriel Marius Burcea Mutcu

Doctoral Candidate

Thais Caroline de Almeida da Silva's picture
Thais Caroline de Almeida da Silva

Doctoral Candidate

Lorenzo Forzanini's picture
Lorenzo Forzanini

Doctoral Candidate

Samiksha Mukesh Jain's picture
Samiksha Mukesh Jain

Doctoral Candidate

Eva Ng's picture
Eva Ng

Doctoral Candidate

Christian Robles's picture
Christian Robles

Doctoral Candidate

Radeya Vasquez's picture
Radeya Vasquez

Doctoral Candidate

Alejandro Saura Avilés's picture
Alejandro Saura Avilés

Graduate Student

PAOLA BALAGUER's picture
PAOLA BALAGUER

Undergraduate Student

Sergio Simarro Ruiz

Undergraduate Student

Publications


2020

Frontiers in Materials, 2020, 7, 273.
Vallés-Pelarda, M.; Sánchez, R.S.; Barea, E.M.; Mora-Seró, I.; Julián-López, B.
Up-Converting Lanthanide-Doped YAG Nanospheres. Materials Advances, 2020, 1, 1202-1211.
Cardenas-Morcoso, D.; Garcia-Tecedor, M.; Merdzhanova, T.; Smirnov, V.; Finger, F.; Kaiser, B.; Jaegermann, W.; Giménez, S.
An Integrated Photoanode Based on Non-Critical Raw Materials for Robust Solar Water Splitting. ACS Applied Energy Materials, 2020,
Han, L.; González-Cobos, J.; Sánchez-Molina, I.; Giancola, S.; Folkman, S.J.; Tang, P.; Heggen, M.; Dunin-Borkowski, R.E.; Arbiol, J.; Giménez, S.; Galán-Mascarós, J.Ramón
Cobalt hexacyanoferrate as a selective and high current densi-ty formate oxidation electrocatalyst. Nanoscale, 2020, x, x.
Hassanabadi, E.; Latifi, M.; Gualdrón-Reyes, A.F.; Masi, S.; Yoon, S.Joon; Poyatos, M.; Julián-López, B.; Mora-Seró, I.
Ligand & band gap engineering: tailoring the protocol synthesis for achieving high-quality CsPbI3 quantum dots. Applied Materials Today, 2020, 20, 100714.
Barrio, J.; Gibaja, C.; Garcia-Tecedor, M.; Abisdris, L.; Torres, I.; Karjule, N.; Giménez, S.; Shalom, M.; Zamora, F.
Electrophoretic deposition of antimonene for photoelectrochemical applications. Energy Technology, 2020, 8, 2000301.
Lemsi, A.; Cardenas-Morcoso, D.; Haro, M.; Gil-Barrachina, C.; Aranda, C.; Maghraoui-Meherzi, H.; Garcia-Tecedor, M.; Giménez, S.; Julián-López, B.
PbS nanocubes for solar energy storage. Nanomaterials, 2020, 10, 872.
Marand, Z.Rezay; Kermanpur, A.; Karimzadeh, F.; Barea, E.M.; Hassanabadi, E.; Anaraki, E.Halvani; Julián-López, B.; Masi, S.; Mora-Seró, I.
Structural and Electrical Investigation of Cobalt-Doped NiOx/Perovskite Interface for Efficient Inverted Solar Cells. ACS Energy Letters, 2020, 5, 187-191.
Cardenas-Morcoso, D.; Bou, A.; Ravishankar, S.; Garcia-Tecedor, M.; Giménez, S.; Bisquert, J.
Intensity-Modulated Photocurrent Spectroscopy for Solar Energy Conversion Devices: What Does a Negative Value Mean?. ACS Applied Materials and Interfaces, 2020, 12, 914−924.
Gualdrón-Reyes, A.F.; Rodríguez-Pereira, J.; Amado-Gonzalez, E.; Rueda-P, J.; Ospina, R.; Masi, S.; Yoon, S.Joon; Tirado, J.; Jaramillo, F.; Agouram, S.; Muñoz-Sanjose, V.; Giménez, S.; Mora-Seró, I.
Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States.


2019

ACS Omega, 2019, 4, 14, 16095−16102.
Shaddad, M.N.; Cardenas-Morcoso, D.; Garcia-Tecedor, M.; Fabregat-Santiago, F.; Bisquert, J.; Al-Mayouf, A.M.; Giménez, S.
TiO2 Nanotubes for Solar Water Splitting: Vacuum Annealing and Zr Doping Enhance Water Oxidation Kinetics. Journal of American Chemical Society, 2019, 141, 47, 18791−18798.
Selim, S.; Pastor, E.; Garcia-Tecedor, M.; Morris, M.R.; Francàs, L.; Sachs, M.; Moss, B.; Corby, S.; Mesa, C.A.; Giménez, S.; Kafizas, A.; Bakulin, A.A.; Durrant, J.Robert
Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes. Organometallics, 2019, 38, 4565-4569.
Gutierrez-Blanco, A.; Ibáñez, S.; Hahn, E.; Poyatos, M.; Peris, E.
A Twisted Tetragold Cyclophane from a Fused Bis-Imidazolindiylidene. ChemNanoMat, 2019, 5, 9, 1188-1201.
Van Renterghem, L.; Guzzetta, F.; Le Griel, P.; Selmane, M.; Ben Messaoud, G.; Teng, T.Tan Su; Lim, S.; Soetaert, W.; Roelants, S.; Julián-López, B.; Baccile, N.
Easy Formation of Functional Liposomes in Water Using a pH‐Responsive Microbial Glycolipid: Encapsulation of Magnetic and Upconverting Nanoparticles. Nanoscale Advances, 2019, 1, 2537-2545.
Gonell, F.; Botas, A.M.P.; Brites, C.D.S.; Amorós, P.; Carlos, L.D.; Julián-López, B.; Ferreira, R.A.S.
Aggregation-induced heterogeneities in the emission of upconverting nanoparticles at the submicron scale unfolded by hyperspectral microscopy. ACS Applied Materials and Interfaces, 2019, 8,11, 16546-16555.
Liu, K.; Wu, L.; Valenti, M.; Cardenas-Morcoso, D.; Hofmann, J.Philipp; Bisquert, J.; Giménez, S.; Smith, W.A.
Electronic effects determine the selectivity of planar Au-Cu bimetallic thin films for electrochemical CO2 reduction. ACS Catalysis, 2019, 9, 3527−3536.
Valenti, M.; Prasad, N.P.; Kas, R.; Bohra, D.; Ma, M.; Balasubramanian, V.; Chu, L.; Giménez, S.; Bisquert, J.; Dam, B.; Smith, W.A.
Suppressing H2 Evolution and Promoting Selective CO2 Electroreduction to CO at Low Overpotentials by Alloying Au with Pd. Advanced Materials Interfaces, 2019, 1900299, 1-8.
Garcia-Tecedor, M.; Cardenas-Morcoso, D.; Fernández-Climent, R.; Giménez, S.
The Role of Underlayers and Overlayers in Thin Film BiVO4 Photoanodes for Solar Water Splitting. Journal of Materials Chemistry A, 2019, 7, 11143-11149.
Cardenas-Morcoso, D.; Ifraemov, R.; Garcia-Tecedor, M.; Liberman, I.; Giménez, S.; Hod, I.
A Metal-Organic Framework Converted Catalyst that Boosts Photo-Electrochemical Water Splitting. Chemical Science, 2019, 10 (9), 2643-2652.
Selim, S.; Francàs, L.; Garcia-Tecedor, M.; Corby, S.; Blackman, C.; Giménez, S.; Durrant, J.Robert; Kafizas, A.
WO3/BiVO4: impact of charge separation at the timescale of water oxidation. ACS Energy Letters, 2019, 4, 337−342.
Moss, B.; Hegner, F.Simone; Corby, S.; Selim, S.; Francàs, L.; López, N.; Giménez, S.; Galán-Mascarós, J.Ramón; Durrant, J.Robert
Unraveling Charge Transfer in CoFe Prussian Blue Modified BiVO4 Photoanodes.